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steric arrangement. Monomer insertion instead of ligand migration is supposed to occur. Pino and Miilhaupt considered four diastereomeric TC complexes formed as a result of the four possible modes of complexation of propylene 28 They suggested that diastereomeric and rotameric equilibria between these TC complexes and/or activation energy for the insertion reaction control the large regioselectivity and enantioface discrimination necessary for stereoregular polymerization. An interesting suggestion regarding the possibility of a carbene mechanism was also raised347 but was disproved by NMR studies lO In the polymerization of propylene with TiCl3 + (13CH3hAII, only labeled methyls but no methylenes were observed. The formation of the latter could be expected if the carbene mechanism were operative. Stimulated by their great industrial importance, high-activity MgCITsupported titanium catalysts have been extensively studied 63-267 MgCl 2 + TiCl 4 treated with alkylaluminum is a highly active catalyst system with poor stereoselectivity (isotacticity index 50-70%). When treated with suitable electron-donor molecules (preferably with aromatic esters) called selectivity control agents, highly selective catalysts are formed. On the basis of structural similarities between MgCl 2 and 0-TiCl 3, and the similar nonselectivity exhibited by ~- TiCl 3 and the nontreated MgCl 2 + TiCl 4 systems, two types of active centers were suggested 48 one with two chlorine vacancies (nonstereoselective site), and the other with one vacancy and one loosely bound chlorine (low isospecificity site). Donor molecules (:D) transform the nonstereoselective sites into highly isospecific centers [Eq. (13.77)], while the low isospecificity site is poisoned: qr code excel generator QR code Generator - MrExcel.com
Does anyone know of any VBA code that can generate a QR code ? ... websites and apps to generate but what about native Excel generation? qr code from excel data QR Code Add-In for MS Excel - Avapose.com
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